Correlations between relaxation time spectrum and melt spinning behavior of polypropylene. 1: Calculation of the relaxation spectrum as a log-normal distribution and influence of the molecular parameters

The linear viscoelastic behavior of commercial broad-distribution polypropylenes is studied. The samples underwent different controlled peroxide degradation rates, so they exhibit different molecular distributions. The relaxation spectrum is obtained by assuming that it takes the shape of a Log-Normal distribution. It is in agreement with the linear viscoelasticity theory by providing limiting values, contrary to other models. Moreover, the ratio τw/τn which takes place in this law is very useful to distinguish the synthesis differences of the samples when the Melt Flow Index alone cannot.     

Multivariate analysis of the correlation between noctuidae subfamilies and the chemical structure of their sex pheromones or male attractants

Female-emitted pheromones and sex attractants of Noctuidae were investigated using a specific computer procedure to analyze data collected from the literature. Correspondence analysis was used to survey the structure-activity relationships of sex pheromones in seven subfamilies. Structural, stereochemical, and functional features of active molecules were related to taxonomy. This multidimensional analysis revealed that the prevalent chemical frame of noctuid moth pheromones was a monounsaturated acetate withZ stereochemistry and a double bond on the fifth carbon closest to the nonfunctional branch of the molecule. Possible phylogenetic relationships within Noctuidae and between Noctuidae and other families are discussed in light of the sex pheromone biochemistry. Female sex pheromones appeared to be an additional character to be considered in the classification of noctuid moths.     

Functionalization of PVC by grafting of plasticizing group in a twin screw extruder

Substitution reactions are an appropriate way to attach chemical functions to polymer chains for improving properties and to diversify the application of polymer materials. The stereoselective substitution of chlorine atoms affords a useful way to plasticize polyvinychloride (PVC) by attaching appropriate plasticizing functions (ester group) such as isooctylthiosalicylate. Thus, the substitution of chlorine atoms of PVC by reactant bearing plasticizing groups was carried out in a continuous mixing apparatus such as a twin screw extruder. This continuous chemical engineering process taking place in the extruder is studied as the function of the residence time distribution (RTD) measured by a UV method. This function combined with the kinetics of the chemical reaction allows to define a new function G as the distribution of the extent of conversion by analogy with the RTD function.     

The effect of the framework structure on the chemical properties of the vanadium oxide species incorporated within zeolites

V-silicalite catalysts (VS-1 and VS-2) prepared by hydrothermal synthesis have been studied by ESR, XAFS (XANES and EXAFS) and photoluminescence spectroscopy. The in situ characterization of these V-silicalites shows that vanadium is present within the zeolitic framework as a highly dispersed tetrahedrally coordinated V-oxides, VO₄ unit, having a short V=O bond length. Photoluminescence spectroscopy in static and dynamic mode, as well as XAFS studies allow to detect in the V-silicalites different V species than that present in V-HMS or V/SiO₂, in terms of V=O bond length, vibrational energy, bond angle and lifetime of the excited triplet state. It is suggested that the combined contribution of the neighboring Si---OH group attached to the VO₄ unit and the zeolitic rigid framework structure of V-silicalites cause a more significant and pronounced effect on the chemical properties of the VO₄ unit than the flexible structure of V-HMS or V/SiO₂. Moreover, the dynamic quenching of the phosphorescence by the addition of reactant molecules such as NO or propane indicates that the V species in the excited triplet state can be expected to be the active sites for the photocatalytic reactions.     

The Future of the Refractory Industry, with a Chinese Perspective

Globalization is a reality resulting in many changes in the refractory industry. In this paper some of the threats and opportunities, which are influencing the future prosperity of the refractory industry on a worldwide basis, are being evoked. Some key technical and management issues are underlined, in terms of adjusting the productivity-quality-cost to the customers requirements ; producing unshapes versus shapes; innovations supported by research; international profile for the import-export game; training and education. Consequences for China, who does play a dominant role due to the size of its internal market （ customers demand） and the magnitude of its production capability （including raw materials availability）, are being drawn.     

Paf-acether in human skin

Paf is a phospholipid mediator present in human skin which induces inflammatory events such as neutrophil infiltration and increased vascular permeability. Recent data suggest that cutaneous cells, such as fibroblasts and keratinocytes, produce paf and that paf is released during allergic cutaneous reactions. It is tempting to speculate that paf may contribute to the development of various skin disorders with acute and chronic skin inflammation. Paf antagonists may help in bringing answers to this hypothesis and may offer new prospects for the treatment of cutaneous inflammatory diseases. Based on a paper presented at the Third International Conference on Platelet-Activating Factor and Structurally Related Alkyl Ether Lipids, Tokyo, Japan, May 1989.     

Fractal Characteristics of Fracture Surfaces

Quantitative fractography is often used to study material failure mechanisms. During calculation of surface or profile roughness parameters, the magnification used in obtaining fractographic data is found to influence the value of the parameters. Fractal geometry has been developed into a tool capable of defining surface and profile topography without sensitivity to magnification, and several studies have related fractal dimension ( D _F) to other physical or mechanical properties. In this study, we obtained the fractal dimension of profiled fracture surfaces of one glass and three proprietary dental porcelains. The fracture toughness ( K _1c) of these materials was also measured using the indentation-strength method. Results show the surfaces to be fractal. No quantitative relationship between fractal dimension and toughness was found. Differences in K _1c were demonstrated between some materials. It is postulated that the size range within which fractal dimension can be defined as constant is dependent on the toughening mechanism, and that the relationship between K _Ic and D _F cannot be identical for all materials.     

Large-scale in vivo synthesis of the carbohydrate moieties of gangliosides GM1 and GM2 by metabolically engineered Escherichia coli

Two metabolically engineered Escherichia coli strains have been constructed to produce the carbohydrate moieties of gangliosides GM2 (GalNAcbeta-4(NeuAcalpha-3)Galbeta-4Glc; Gal = galactose, Glc = glucose, Ac = acetyl) and GM1 (Galbeta-3GalNAcbeta-4(NeuAcalpha-3)Galbeta-4Glc. The GM2 oligosaccharide-producing strain TA02 was devoid of both beta-galactosidase and sialic acid aldolase activities and overexpressed the genes for CMP-NeuAc synthase (CMP = cytidine monophosphate), alpha-2,3-sialyltransferase, UDP-GlcNAc (UDP = uridine diphosphate) C4 epimerase, and beta-1,4-GalNAc transferase. When this strain was cultivated on glycerol, exogenously added lactose and sialic acid were shown to be actively internalized into the cytoplasm and converted into GM2 oligosaccharide. The in vivo synthesis of GM1 oligosaccharide was achieved by taking a similar approach but using strain TA05, which additionally overexpressed the gene for beta-1,3-galactosyltransferase. In high-cell-density cultures, the production yields for the GM2 and GM1 oligosaccharides were 1.25 g L(-1) and 0.89 g L(-1), respectively.     

Modelling of the Nonlinear Behavior of Compatibilized Polyethylene/Polyamide Blends in Shear and Extensional Flows

We have studied the effect of the amount Φ_c of a reactive compatibilizer on the rheological properties of a polyethylene/polyamide blend, under steady shear and transient extensional flows. Here, we propose to describe the viscosity η(γ) and the first normal stress coefficient γ₁(γ) using a Carreau‐type power‐law model, which is a three‐parameter model. A single model is sufficient to express the behavior of γ₁(γ) On the other hand, the complete η(γ) curve is described by the superposition of two Carreau models, in relation to the presence of two relaxation mechanisms. Moreover, the extentional viscosity η_E(?), estimated using the end pressure drop observed in capillary flow experiments, is expressed by a two‐parameter power‐law model.